閫氳繃C-H閿椿鍖栬姵鍩哄寲鍙嶅簲鍚堟垚鑱旇姵鍖栧悎鐗╀竴鐩存槸緇胯壊鍖栧浠ュ強鑽墿鍚堟垚棰嗗煙鐨勭爺絀跺墠娌垮拰閲嶇偣銆傝櫧鐒朵紶緇熺殑鍧囩浉鍌寲鍓傚湪璇ラ鍩熷彇寰椾簡宸ㄥぇ鐨勬垚鍔燂紝浣嗘槸鍌寲鍓傜殑鐢ㄩ噺澶с侀毦鍥炴敹鍒╃敤鍜屼駭鐗╅毦鍒嗙錛岃屼笖鍌寲榪囩▼涓鑸渶瑕佹瘮杈冭嫑鍒葷殑鏃犳按鐜錛屽鍔犱簡澶ц妯″悎鎴愮殑鎴愭湰騫朵笖閫犳垚涓瀹氱殑鐜姹℃煋銆?
鍦ㄧ鎶閮?73璁″垝銆佸浗瀹惰嚜鐒剁瀛﹀熀閲戦」鐩瓑鐨勬敮鎸佷笅錛岀寤虹墿鏋勬墍緇撴瀯鍖栧鍥藉閲嶇偣瀹為獙瀹ゆ浌鑽ｈ棰樼粍鍦ㄧ洿鎺-H閿椿鍖栬姵鍩哄寲鍙嶅簲鍚堟垚澶氭盁鑱旇姵鍖栧悎鐗╃殑鐮旂┒涓彇寰楅噸瑕佽繘灞曘傝鐮旂┒灝忕粍鍒╃敤鐡滅幆浣滀負杞戒綋錛岄噰鐢ㄧ畝鍗曠殑涓閿呮硶鐩存帴鍚堟垚浜嗙矑寰勫皬浜?綰崇背鍒嗘暎鍧囧寑鐨凱d綰崇背棰楃矑澶嶅悎鏉愭枡錛岃鏉愭枡鍦ㄨ繖綾誨弽搴斾腑琛ㄧ幇鍑哄緢楂樼殑媧繪э紝鍌寲鍓傜敤閲忓皯銆佸弽搴旀潯浠舵俯鍜屻佷笉闇瑕侀櫎姘撮櫎姘с佽兘澶熷湪絀烘皵涓繘琛岋紝騫朵笖鏈夌潃騫挎硾鐨勫畼鑳藉洟瀹瑰繊鎬у強鑹ソ鐨勫驚鐜嬌鐢ㄦц兘錛屽睍紺轟簡浼樺紓鍌寲鏁堢巼鍜岄夋嫨鎬с傝灝忕粍榪樼爺絀朵簡涓嶅悓鍏冩暟鐨勭摐鐜墍褰㈡垚鐨凱d綰崇背澶嶅悎浣撳拰鍌寲鎬ц兘涔嬮棿鐨勬瀯鏁堝叧緋伙紝騫朵笖閫氳繃瀹為獙楠岃瘉浜嗗紓鐩稿偓鍖栫殑鏈虹悊銆傚煎緱娉ㄦ剰鐨勬槸錛岃繖涔熸槸棣栨鍒╃敤綰崇背棰楃矑鎴愬姛瀹炵幇鍌寲鐩存帴C-H閿椿鍖栧悎鎴愬姘熻仈鑺沖寲鍚堢墿錛屽叿鏈夊緢濂界殑搴旂敤鍓嶆櫙錛岀浉鍏崇爺絀舵垚鏋滃彂琛ㄥ湪J. Catal., 2015錛?21錛?2-69涓娿?
