鍖栧鎵澶氬瓟鑱氬悎鐗╂潗鏂欐崟闆嗗拰鍌寲CO2杞寲鐮旂┒鑾瘋繘灞?/span>
2016-9-22 鏉ユ簮:涓浗鑱氬悎鐗╃綉 鐐瑰嚮嬈?/span>
鍏抽敭璇嶏細(xì)澶氬瓟鑱氬悎鐗?/a> 鐮旂┒
CO2鏄富瑕佺殑娓╁姘斾綋錛屽悓鏃朵篃鏄粔浠楓佷赴瀵岀殑C1璧勬簮錛孋O2鐨勬崟闆嗗拰鍖栧杞寲鍏鋒湁閲嶈鎰忎箟銆傚瀛旇仛鍚堢墿鏉愭枡鍥犲叾緇撴瀯銆佸姛鑳界殑鍙璁℃э紝鍦ㄦ皵浣撳惛闄勫垎紱匯佸寲瀛﹀偓鍖栫瓑棰嗗煙鏄劇ず鍑哄箍闃旂殑搴旂敤鍓嶆櫙錛屼負(fù)CO2鐨勬崟闆嗗拰鍌寲杞寲鎻愪緵浜嗗彂灞曞鏈恒?br />
鍦ㄥ浗瀹惰嚜鐒剁瀛﹀熀閲戝鍜屼腑鍥界瀛﹂櫌鐨勫ぇ鍔涙敮鎸佷笅錛屼腑縐戦櫌鍖栧鐮旂┒鎵鑳朵綋銆佺晫闈笌鍖栧鐑姏瀛﹂噸鐐瑰疄楠屽鍒樺織鏁忚棰樼粍縐戠爺浜哄憳鍦ㄥ瀛旇仛鍚堢墿鏉愭枡璁捐鍚堟垚鍙?qiáng)鍏舵崟闆嗗拰鍌寲CO2杞寲鏂歸潰寮灞曚簡緋葷粺鐮旂┒錛屽彇寰楁柊榪涘睍銆傜爺絀朵漢鍛橀氳繃鍦ㄨ仛鍚堢墿緇撴瀯涓紩鍏ヤ翰CO2鍩哄洟錛屽彂灞曚簡澶氱鍚愛(Chem. Commun. 2015, 51, 1271;Chem. Commun. 2015, 51, 11576.)銆佸惈姘?Green Chem. 2014, 16, 3724;Chem. Commun. 2014, 50, 13910.)銆佸惈鑶?ACS Catal. 2016, 6, 1268.)鐨勫姛鑳藉寲澶氬瓟鑱氬悎鐗╁偓鍖栨潗鏂欙紝瀹炵幇浜咰O2鐨勬湁鏁堟崟闆嗗拰楂樻晥杞寲銆?br />
鏈榪戯紝鐮旂┒浜哄憳閫氳繃澶氬彇浠ｈ姵棣欒兒涓庡閰氬伓鑱斿弽搴旓紝鍦ㄦ棤妯℃澘銆佹俯鍜屾潯浠朵笅錛岄嬈″湪姘寸浉浣撶郴涓悎鎴愪簡鑱氬伓姘厷浠嬪瓟鏉愭枡銆傛墍寰楁潗鏂欑殑姣旇〃闈㈢Н楂樿揪593 m2 g-1錛?鍏朵腑~80%鏉ヨ嚜浠嬪瓟璐＄尞;鏉愭枡緇撴瀯涓伓姘敭鍜岄厷緹熷熀鐨勫瓨鍦ㄤ嬌鏉愭枡鍏鋒湁鑹ソ鐨勬阿閿艦鎴愯兘鍔涘拰铻悎閲戝睘鑳藉姏銆傝鏉愭枡鍙珮鏁堝惛闄凜O2錛屽茍瀵瑰惛闄勫垎紱籆O2鍜孨2鏄劇ず鑹ソ鐨勫垎紱婚夋嫨鎬с傝灟鍚堜簡Zn2 鐨勮仛鍚堢墿鏉愭枡涓庡洓涓佸熀婧村寲閾靛叡鍚屼綔鐢紝鍙湪甯告俯甯稿帇涓嬮珮鏁堝偓鍖朇O2涓庣幆姘т笝鐑風(fēng)殑鐜姞鎴愬弽搴?Angew. Chem. Int. Ed. 2016, 55, 9685; highlighted in back cover)銆?br />
鍏嶈矗澹版槑錛氶儴鍒嗚祫鏂欐潵婧愪簬緗戠粶錛岃漿杞界殑鐩殑鍦ㄤ簬浼犻掓洿澶氫俊鎭強(qiáng)鍒嗕韓錛屽茍涓嶆剰鍛崇潃璧炲悓鍏惰鐐規(guī)垨璇佸疄鍏剁湡瀹炴э紝
涔熶笉鏋勬垚鍏朵粬寤鴻銆備粎鎻愪緵浜ゆ祦騫沖彴錛屼笉涓哄叾鐗堟潈璐熻矗銆傚娑夊強(qiáng)渚墊潈錛岃鑱旂郴鎴戜滑鍙?qiáng)鏃朵慨鏀规垨鍒犻櫎銆?br>閭錛歩nfo@polymer.cn
錛堣矗浠葷紪杈戯細(xì)liu錛?
