Supramolecular gel-to-gel transition induced by nanoscale structural perturbation via the rotary motion of Feringa’s motor
作者：Yunan Qin et al
關(guān)鍵字：molecular machines, molecular motor, multicomponent gel, gel-to-gel transition, crystallographic mismatch branching
論文來源：期刊
具體來源：Small, 2023. https://doi.org/10.1002/smll.202207785
發(fā)表時間：2023年
Supramolecular rather than covalent molecular engineering on Feringa motors can provide an alternative toolkit for tuning the properties of motorized materials through appropriate supramolecular structural perturbations, which are underexplored. Herein, a multicomponent supramolecular gel system was successfully prepared by employing an ultra-low molecular weight gelator and a modulator-Feringa motor. The electron microscopic, spectroscopic and rheological data revealed that the morphology and mechanical properties of the gel could be tuned via a crystallographic mismatch branching (CMB) mechanism simply by adding varied amounts of motor modulators. Notably, the rotary motion of the motor was preserved in such a multicomponent gel system, and the morphology and rheology of the gel can be further altered by the motor’s rotary motion that promotes the structural perturbation, resulting in seldomly seen gel-to-gel transition events. Our work shown here offers prospects to utilize a supramolecular perturbation strategy to deliver responsiveness from molecular motors to the corresponding bulk materials.