私密直播全婐app免费大渔直播,国产av成人无码免费视频,男女同房做爰全过程高潮,国产精品自产拍在线观看

相關鏈接
聯系方式
  • 通信地址:加拿大魁北克省蒙特利爾
  • 郵編:無
  • 電話:(514) 848-2424 ext.5611
  • 傳真:
  • Email:zhibin.ye@concordia.ca
當前位置:> 首頁 > 論文著作 > 正文
Hyperbranched-linear polyethylene block polymers constructed with chain blocks of hybrid chain topologies via one-pot stagewise chain walking ethylene ‘living’ polymerization
作者:Y. Xu, P. Xiang, Z. Ye*, W.-J. Wang
關鍵字:無
論文來源:期刊
具體來源:Macromolecules
發表時間:2010年
We demonstrate in this article the facile synthesis of a novel range of “treelike” polyethylene block polymers constructed uniquely with chain blocks of hybrid hyperbranched?linear chain topologies from sole ethylene stock. Though chemically identical, the blocks in the polymers are featured with distinctly different chain topologies, varying from hyperbranched to linear. This synthesis is achieved uniquely through one-pot stagewise chain walking ethylene “living” polymerization with a Pd?diimine catalyst, [(ArN═C(Me)?(Me)C═NAr)Pd(CH3)(N≡CMe)]+SbF6? (Ar = 2,6-(iPr)2C6H3) (1), under varying conditions. It takes advantage of the combined outstanding features of the Pd?diimine catalyst in ethylene polymerization—the “living” polymerization behavior at a broad range of ethylene pressure and temperature and the capability of topology tuning by changing both parameters. In this stagewise “living” polymerization technique, the polymerization condition (ethylene pressure and temperature) is varied from stage to stage to grow blocks of different desired topologies while with maintained “living” behavior. With this technique, diblock polymers, containing a hyperbranched first block and a linear second block with controllable narrow-distributed sizes, have been obtained through two-stage polymerizations using the growth order of “hyperbranched-first” with the first stage at 1 atm/15 °C and the second stage at 27 atm/5 °C. The distinct block structure in these diblock polymers is verified based on the fact that their intrinsic viscosity data follow consistently the combination rule found with conventional diblock polymers. In addition, the synthesis of triblock polymers, composed of a hyperbranched first block, a medium-compact second block, and a linear third block, is also demonstrated through three-stage polymerization involving the first stage at 1 atm/15 °C, the second at 3 atm/15 °C, and the third at 27 atm/5 °C.
主站蜘蛛池模板: 巴林左旗| 报价| 嵊泗县| 大埔区| 丰原市| 平和县| 阿拉尔市| 安徽省| 淳化县| 瓦房店市| 乐至县| 合川市| 尉氏县| 瓦房店市| 苏尼特左旗| 杨浦区| 邳州市| 海晏县| 南通市| 宜城市| 洪泽县| 集贤县| 重庆市| 溧水县| 九寨沟县| 江川县| 肃宁县| 额敏县| 潼南县| 常德市| 苍山县| 莎车县| 固始县| 彭泽县| 京山县| 杂多县| 新巴尔虎左旗| 定襄县| 黔西| 五原县| 秦皇岛市|