A Pd?diimine catalytic inimer for synthesis of polyethylenes of hyperbranched-on-hyperbranched and star architectures
作者：L. Xu, Z. Ye*
關(guān)鍵字：無(wú)
論文來源：期刊
具體來源：Chemical Communications
發(fā)表時(shí)間：2013年
A Pd-diimine catalytic inimer containing uniquely catalytic, initiating, and monomeric functionalities in one catalyst molecule is designed. It enables the first self-condensing vinyl copolymerization of ethylene, leading to polyethylenes of a hyperbranched-on-hyperbranched architecture. Meanwhile, it also facilitates the synthesis of star polyethylenes by tandem UV-coordinative polymerization.