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Star-like supramolecular polymers fabricated by a Keplerate cluster with cationic terminated polymers and their self-assembly into vesicles
writer:Qian Zhang, Lipeng He, Hui Wang, Cheng Zhang, Weisheng Liu and Weifeng Bu
keywords:Polyoxometalates, Star Polymers, Vesicles, Solvent Quality
source:期刊
specific source:Chem. Commun. 2012, 48, 7067–7069
Issue time:2012年
The electrostatic combination of a Keplerate cluster, [Mo132O372(CH3COO)(30)(H2O)(72)](42-) with cationic terminated poly(styrene) yields polyoxometalate-based supramolecular star polymers, which can further self-assemble into vesicular aggregates in CHCl3-MeOH mixed solvent.