Preparation and Rheological Behaviors of Thermoplastic Poly(vinyl alcohol) Modified by Lactic Acid
作者：Jing Ding, Si-Chong Chen,* Xiu-Li Wang, and Yu-Zhong Wang*
關(guān)鍵字：Thermoplastic Poly(vinyl alcohol)
論文來源：期刊
具體來源：Industrial & Engineering Chemistry Research
發(fā)表時間：2011年
A thermoplastic modified poly(vinyl alcohol) (PVA-g-LA) with improved melt processing property was prepared bymelt polycondensation of PVA with lactic acid. Rheological behaviors of PVA-g-LA copolymers were investigated using a highpressure capillary rheometer. The influences of the content of oligo-poly (lactic acid) graft chains and content of PVA-0588 on the rheological properties of PVA-g-LA copolymers were researched. The rheological parameters including non-Newtonian index and the viscous flow activation energy were analyzed and evaluated. As predicted, the PVA-g-LA samples exhibited noticeable shear thinning behavior. The apparent viscosity, the viscous flow activation energy, and the non-Newtonian index of PVA-g-LA showed obvious correlation with the PLA grafting chain content and PVA-0588 content at a constant temperature and shear rate. Both the increase of the content of oligo-PLA graft chains and content of PVA-0588 with PVA-1799 can improve the melting flow processing of PVA-g-LA copolymer.