Ordered macroporous films from self-assembly of two-armed polymer with a crown ether core
作者：Fu, J.; et al.
關(guān)鍵字：macroporous films, self-assembly, two-armed polymer
論文來(lái)源：期刊
具體來(lái)源：Polymer, 2004, 45, 7389-7394.
發(fā)表時(shí)間：2004年
Highly ordered honeycomb-like macroporous films were obtained via self-assembly of a two-armed polymer with a crown ether core under controlled conditions. A possible mechanism is speculated, primarily based on the strong affinity between the crown ether cores. The pore size and arrangement are sensitive to the solvent evaporation rate and the solution concentration. Upon spontaneous drying, the pore diameter (D) depends on the concentration (c) by a relation of D = 518 c -0.610.