【Journal of Hazardous Materials， IF=10.588】L-proline-based deep eutectic solvents (DESs) for deep catalytic oxidative desulfurization (ODS) of diesel
作者：郝凌婉等
關鍵字：IONIC-LIQUIDROOM-TEMPERATUREHYDROGEN-PEROXIDEMODEL DIESELEXTRACTIVE DESULFURIZATIONBIGINELLI REACTIONCHOLINE CHLORIDEDUAL ACTIVATIONTHIOPHENEFUELS
論文來源：期刊
具體來源：JOURNAL OF HAZARDOUS MATERIALS
發表時間：2017年
A series of L-proline-based DESs was prepared through an atom economic reaction between L-proline (L-Pro) and four different kinds of organic acids. The DESs were characterized by Fourier transform infrared spectroscopy (FT-IR), H nuclear magnetic resonance ((HNMR)-H-1), cyclic voltammogram (CV) and the Hammett method. The synthesized DESs were used for the oxidative desulfurization and the L-Pro/p-toluenesultonic acid (L-Pro/p-TsOH) system shows the highest catalytic activity that the removal of dibenzothiophene (DBT) reached 99% at 60 degrees C in 2 h, which may involve the dual activation of the L-Pro/p-TsOH. The acidity of four different L-proline-based DESs was measured and the results show that it could not simply conclude that the correlation between the acidity of DESs and desulfurization capability was positive or negative. The electrochemical measurements evidences and recycling experiment indicate a good stability performance of L-Pro/p-TsOH in desulfurization. This work will provide a novel and potential method for the deep oxidation desulfurization. (C) 2017 Elsevier B.V. All rights reserved.