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60. Core-Shell Structured Polyamide 66 Nanofibers with Enhanced Flame Retardancy
作者:L. Xiao, L. Xu, Y. Yang, S. Zhang, Y. Huang, C. W. Bielawski, J. Geng,*
關鍵字:Fire-retardant, Carbon nanotubes, Polymer, Nanocomposites, Composite, Layer
論文來源:期刊
具體來源:ACS Omega 2017, 2, 2665–2671
發表時間:2017年

We report the preparation of polymer nanofibers with enhanced flame retardancy by coaxial electrospinning polyamide 66 (PA 66) and nanoscale graphene hybridized with red phosphorus (NG-RP). Transmission electron microscopy and energy-dispersive X-ray spectroscopy revealed that the nanofibers contained a NG-RP-based core surrounded by a PA 66 shell. The flame-retardant characteristics of the nanofibers were investigated by thermal gravimetric analysis, micro combustion calorimetry, and a series of vertical flame tests. The encapsulation of the NG-RP not only enhanced the flame-retardant characteristics of the nanofibers, but also improved their mechanical properties while maintaining the color and luster of the polymer, making the resultant nanofibers appropriate for use in a wide range of applications.

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