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68. Synthesis of Macroporous Conjugated Polymer Framework: Iron Doping for Highly Stable, Highly Efficient Lithium–Sulfur Batteries
作者:P. Jia, T. Hu, Q. He, X. Cao, J. Ma, J. Fan, Q. Chen, Y.-H. Ding, J. Pyun, J. Geng,*
關鍵字:Macroporous conjugated polymer, Graphene, SI-KCTP, Iron doping, Lithium-sulfur batteries
論文來源:期刊
具體來源:ACS Appl. Mater. Interfaces 2019, 11, 3087–3097
發表時間:2019年
Porous conjugated polymers offer enormous potential for energy storage because of the combined features of pores and extended pi-conjugated structures. However, the drawbacks such as low pore volumes and insolubilities of micro- and mesoporous conjugated polymers restrict the loading of electroactive materials and thus energy storage performance. Herein, we report the synthesis of iron-doped macroporous conjugated polymers for hosting sulfur as the cathode of high-performance lithium-sulfur (Li-S) batteries. The macroporous conjugated polymers are synthesized via in situ growth of poly(3-hexylthiophene) (P3HT) from reduced graphene oxide (RGO) sheets, followed by gelation of the composite (RGO-g-P3HT) in p-xylene and freeze-drying. The network structures of the macroporous materials can be readily tuned by controlling the chain length of P3HT grafted to RGO sheets. The large pore volumes of the macroporous RGO-g-P3HT materials (ca. 34 cm(3) g(-1)) make them excellent frameworks for hosting sulfur as cathodes of Li-S batteries. Furthermore, incorporation of Fe into the macroporous RGO-g-P3HT cathode results in reduced polarization, enhanced specific capacity (1,288, 1,103, and 907 mA h g(-1) at 0.05, 0.1, and 0.2 C, respectively), and improved cycling stability (765 mA h g(-1) after 100 cycles at 0.2 C). Density functional theory calculations and in situ characterizations suggest that incorporation of Fe enhances the interactions between lithium polysulfides and the P3HT framework.
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