[Macromolecules] Synthesis and Stereospecific Polymerization of a Novel Bulky Styrene Derivative
writer：Rong Wang#, Dongtao Liu#(共同一作), Xiaohong Li, Jie Zhang, Cui Dongmei*, Xinhua Wan*
keywords：Stereospecific Polymerization, Bulky Styrene Derivative
source：期刊
Issue time：2016年
A novel vinylbiphenyl monomer, 2-methoxy-5-phenylstyrene (MOPS), was designed and efficiently synthesized to investigate the stereospecific polymerization of bulky and polar styrenic derivative. Regardless of its large side group and electron-donating o-methoxy substituent, this compound showed a high polymerizability and was readily converted to the corresponding polymers with moderate to high molecular mass through radical, anionic, and coordination polymerizations.