172. Fabrication of electrically conductive graphene/polystyrene composites via a combination of latex and layer-by-layer assembly approaches.
作者：Fan W.; Zhang C.; Tjiu W. W.; Liu T. X.*
關鍵字：Polystyrene, Graphene, Composites, Assembly
論文來源：期刊
具體來源：J. Mater. Res., 2013, 28(4), 611-619.
發(fā)表時間：2013年
Due to its excellent physical properties, graphene acting as reinforcing fillers has attracted intense interests. To achieve a controlled distribution, the formation of a conductive network composed of graphene sheets within polymer matrix is of critical importance. In this work, polystyrene (PS) microspheres wrapped by graphene oxide (GO) sheets were prepared via layer-by-layer (LBL) assembly of oppositely charged GO sheets onto PS microspheres. The deposited GO was then
reduced, and the composite films with a graphene conductive network were prepared by hot pressing. The morphology of graphene conductive network was studied, and the thermal and electrical properties of the composite films were measured. The as-prepared composites showed an improved thermal stability as well as electrical conductivity with a percolation threshold as low as 0.2 vol%. The combination of latex technology and LBL self-assembly method thus demonstrated an efficient and facile approach to fabricate electrically conductive graphene/polymer composites.