Journal of Materials Science & Technology：通過構建陽離子-π相互作用改善石墨在生物降解淀粉材料中的分散和剝離：實現電磁屏蔽增強
論文摘要：Herein, a low-cost, biodegradable, and high-performance microwave shielding graphite/starch mate- rial was fabricated via constructing a cation- πinteraction between ammonium ions and graphite. The graphite flakes and starch were firstly mixed with distilled water containing ammonium hydroxide to form graphite/starch slurry under an ultrasonic assistant. The cation- πinteraction could improve delam- ination degree and dispersion of graphite in starch matrix. The slurry was first used as a coating material on the surface of wood and paper to develop shielding packages. The effect of coating thickness and coating layers on EM shielding property of the materials was investigated. Second, the composites with a high orientation of graphite were fabricated by compression at high pressures. The electrical conductivity and EM shielding effectiveness (SE T ) of the materials were greatly enhanced by construction of cation- πinteraction and orientation of graphite. Specifically, the EM SE T values increased from 56.9 to 66.8 dB for the composites with 50 wt.% graphite and 2.0 mm in thickness by constructing cation- πinteraction. The EM SE T values raised from 17.4 to 66.8 dB via the graphite orientation in the materials with the same components and thickness. The shielding mechanism of the compressed composites with orientation dispersion of graphite was also discussed in comparison to the coating layer with random dispersion of graphite.
全文鏈接：https://doi.org/10.1016/j.jmst.2022.04.045