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Synthesis and Catalytic Oxidation Properties of Polymer-Bound Cobalt Complexes
來源:王榮民教授個人網(wǎng)站 發(fā)布日期:2010-10-25
作者:ZI-QIANG LEI, XIAN-GEN HAN, YU-LAI HU, RONG-MIN WANG, YUN-PU WANG
關鍵字:polymer-bound cobalt complexes; catalysts; alkylbenzenes; cobalt complexes;
論文來源:期刊
具體來源:J Appl Polym Sci 75: 1068–1074, 2000
發(fā)表時間:2000年

Polymer-bound 2,29-bipyridine cobalt complexes PSBPY-Co, PSBPY-Cobipy,
PSBPY-Co-oxine, and PSBPY-Co-phen (where PSBPY: polystyrene bound-2,29-
bipyridine; bipy: 2,29-bipyridine; phen: 1,10-phenanthroline) were synthesized and
investigated by IR, X-ray photoelectric spectroscopy, thermogravimetry–differential
thermal analysis, inductively coupled plasma atomic emission spectrometry, and elemental analysis. The complexes were found to be catalysts for the oxidation of alkylbenzenes and cyclohexene in the presence of molecular oxygen in the absence of solvent.

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