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Vibrational Activity Change of Self-Assembled Monolayers upon Chemical Attachment and Nanoscale Block Revealed by Surface Enhanced Raman Spectroscopy
來源:盧曉林研究員個人網站 發布日期:2014-08-11
作者:ZHOU Jie LI Bo-Lin ZHU Pei-Zhi LU Xiao-Lin*
關鍵字:Vibrational activity, SAM, SERS, high-order effect, symmetry
論文來源:期刊
具體來源:Acta Phys. -Chim. Sin. 2014, 30, 623-627
發表時間:2014年


This paper presents an experimental framework aiming at identifying the origin of weak ambiguous vibrational modes in surface enhanced Raman scattering (SERS), i.e. from the high-order effect or symmetry change using 1,4-benzenedithiol (BDT) as probing molecules. The experimental result indicated the appearance of the weak ambiguous vibrational modes was caused by symmetry change rather than high-order effect. Our experimental method can feasibly be extended to a broad range of targets, for example similar systems excited by lasers with different wavelengths or microelectronic junctions bridged by organic molecules.

http://chinesesites.library.ingentaconnect.com/content/apcs/apcs/2014/00000030/00000004/art00003

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