[Polym. Chem.] Miktoarm star polymers with poly(N-isopropylacrylamide) or poly(oligo(ethylene glycol) methacrylate) as building blocks: synthesis and comparison of thermally-responsive behaviors
作者：Cheng-guang Mu, Xiao-dong Fan,* Wei Tian,* Yang Bai and Xiang Zhou
關(guān)鍵字：Miktoarm star polymers，Thermally-responsive behaviors
論文來(lái)源：期刊
具體來(lái)源：Polym. Chem., 2012, 3, 1137–1149
發(fā)表時(shí)間：2012年
We synthesized two thermally-responsive miktoarm star polymers in which poly(Nisopropylacrylamide) (PNIPAM) or poly(oligo(ethylene glycol) methacrylate) (POEGMA) served as the thermosensitive building blocks.The obtained miktoarm star polymers were comprised of a b-CD core, a PEG arm and about six PNIPAM or POEGMA arms. Furthermore, the thermally-responsive behaviors of the miktoarm star polymers were investigated by a combination of UV-vis spectroscopy, DLS, TEM, 1H NMR,
fluorescence spectroscopy and DCS.The architecture of the nano-assemblies formed by PEGCD-PNIPAMx or PEG-CD-POEGMAx was affected by the thermally-induced dehydration of the polymers.
全文鏈接：
http://pubs.rsc.org/en/content/articlelanding/2012/py/c2py20029e#!divAbstract