Preparation of Poly(ionic liquid) Nanoparticles through RAFT/MADIX Polymerization-Induced Self-Assembly
作者:Qi Zhang, Milin Fu, Chengjian Wang, Jianli Wang,Shiping Zhu
關(guān)鍵字:Poly(ionic liquid) Nanoparticles,RAFT/MADIX PISA
論文來(lái)源:期刊
具體來(lái)源:Polymer Chemistry
發(fā)表時(shí)間:2017年
We report herein a facile method for hierarchical regulation of the morphology of poly(ionic liquid) (PIL) nanoparticles through RAFT/MADIX aqueous polymerization-induced self-assembly of 3-n-dodecyl-1-vinylimidazolium bromide, by using PEG-xanthate as the macro-CTA. Rigid straight rods were formed over a broad composition range even at low solids, due to the high
incompatibility between the charged PIL block and the neutral PEG block.