83. Gelation and Fluorescent Organogels of a Complex of Perylenetetracarboxylic Tetraacid with Cationic Surfactants
作者：Xiangyu Ren, Wei Yu, Zijian Zhang, Nan Xia, Guihua Fu, Xiuping Lua, Wei Wang,
關(guān)鍵字：Organogels; Fluorescence; Perylene; π–π stacking
論文來(lái)源：期刊
具體來(lái)源：Colloids and Surfaces A: Physicochemical and Engineering Aspects
發(fā)表時(shí)間：2011年
In the work we report the formation of fluorescent organogels in toluene of a complex of perylenetetracarboxylic tetraacid (PTCTA) with four cationic surfactants. We found that the gel formation is a function of the gelation temperature and solution concentration. The TEM characterization indicates twisted- or straight-belt aggregates formed in gel-phase or in crystals. The further XRD characterization illustrated a layered structure of complex molecules in these aggregates, mainly driven by π–π stacking of the rigid perylene cores. The UV/vis and fluorescence spectra show the H-type aggregates in the gel-phase. The changes of the aggregate morphology and molecular packing structures with the gelation temperature and solution concentration reflect a competition between gelation and crystallization under the conditions used and the details are discussed in text.