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Nonisothermal crystallization kinetics of bio-based semi-aromatic polyamides
作者:Xueke Sun*, Kancheng Mai, Chuanhui Zhang, Min Cao, Yingying Zhang,Xinghong Zhang
關鍵字:poly(decamethylene terephthalamide),Nonisothermal crystallization kinetics,Biobased,Semi-aromatic polyamides
論文來源:期刊
具體來源:J Therm Anal Calorim (2017) 130:1021–1030
發表時間:2017年

Semi-aromatic copolyamides PA10T10I and PA10T10F based on bio-based poly(decamethylene

terephthalamide) (PA10T) were synthesized by a two-step polycondensation technique. The nonisothermal crystallization of these semi-aromatic polyamides was investigated by differential scanning calorimetry. Avrami theory modified by Jeziorny and Mo equation was used to describe the nonisothermal crystallization kinetics of these semi-aromatic polyamides, respectively. The crystallization activation energies were obtained by Kissinger method. The crystallization temperature, crystallization rate and activation energy were explained by regularity and flexibility of chain.


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