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A general quantitative structure-property relationship treatment for dielectric constants of polymers
作者:Jie Xu, Lei Wang, Guijie Liang, Luoxin Wang, Xiaolin Shen
關鍵字:dielectric constants, QSPR
論文來源:期刊
具體來源:Polymer Engineering and Science
發表時間:2011年
The dielectric constant (e) of a polymer represents thecapacitance of the polymer relative to a vacuum and is important in many industrial applications. Nevertheless, accurate experimental e values of polymers are often unavailable, and current prediction methods lack universality and suitability. Reported here is the development and testing of a new QSPR (quantitative structure property relationship) correlation of e for polymers. The entire set of 57 polymers was divided into a training set of 45 polymers and a test set of 12 polymers according to Kennard and Stones algorithm. A ninedescriptor model, with squared correlation coefficient (R2) of 0.9384 and standard error of estimation (s) of 0.0873, was produced by using the stepwise multilinear regression analysis (MLRA) on the training set. The reliability of the proposed model was further illustrated using various evaluation techniques: leave-one-out cross-validation procedure, randomization tests, and validation through the test set.
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