曾憲順 博士,研究員,博士生導師,教育部新世紀優秀人才。
曾憲順博士,研究員,博士生導師,教育部新世紀優秀人才。主要從事分子生物信息材料與物理相關的熒光分子傳感器、熒光分子探針的研究。在Chem. Eur. J.; Chem. Commun.; J. Org. Chem.;Organometallics; Inorg. Chem.; J. Mater. Chem.; Adv. Funct. Mater.; Org. Biomol. Chem.; Tetrahedron Lett.等國內外期刊發表論文90余篇,SCI收錄70多篇,EI同時收錄30余篇,其中SCI影響因子大于3.0的論文40多篇,被SCI源論文正面引用近1200次,申報發明專利6項,2006年獲天津市自然科學二等獎1項;2009年入選“教育部新世紀優秀人才支持計劃人選”;2013年入選天津市 “131”創新型人才培養工程第一層次人選。
2001年獲得南開大學理學博士學位;2001年7月-2005年6月在南開大學任講師、副教授;2003年7月-2004年8月在Université du Havre/巴黎大學(V)法國國家研究中心(CNRS)做博士后;2004年9月-2006年8月在英國杜倫大學做EPSRC博士后;2006年9月-2007年6月在巴黎大學(V)法國國家研究中心(CNRS)做博士后;2007年7月至今天津理工大學任特聘教授;2008年7月-2008年9月在巴黎大學(V)法國國家研究中心(CNRS)做訪問教授;2010年受聘哈爾濱工業大學材料科學與工程學院外聘博士生導師。
課題組研究領域:
課題組的研究工作主要圍繞于材料科學、生物醫學、信息材料科學,以材料分子與結合目標之間作用產生的光/電信息為主要研究對象。開展包括熒光分子傳感器、電化學分子傳感器、生物熒光探針等領域的研究工作。通過對有機、高分子、納米等熒光或電活性探針材料的優化設計,采用熒光成像技術、熒光光譜分析、電化學分析等信號分析手段來研究探針材料與實際醫藥分析檢測、活細胞或活體動物之間作用時產生的光電信號,并通過對信號的分析處理實現對活體離子檢測評價、癌癥等重大疾病的早期檢測。
主要研究方向包括:
1. 化學和生物熒光小分子傳感探針。
2. 靶向和智能熒光小分子生物探針。
1)靶向熒光小分子生物探針
通過對探針材料的靶向設計,開發發光性能穩定、生物相融強、靶向選擇性高的生物熒光探針材料,并探索在腫瘤早期檢測等領域的應用。
2)智能熒光小分子生物探針
通過熒光共振能量轉移原理(FRET)或生物分子靶原理設計針對目標檢測物的各種智能熒光小分子生物探針。
3. 光/電聚合物生物傳感探針。
研究生人才培養:
課題組從成立以來已培養碩士研究生6人,分別就業于大中型生物醫藥企業和光電子企業;目前有在讀博士研究生1人,在讀研究生15人。
1.課題組每年招收化學和生物專業的碩士研究生3-5人;
2. 課題組每年招收化學專業或生物專業的博士研究生1-2人(哈爾濱工業大學學位)。
歡迎有志于生物醫用材料的學生報考課題組的碩士研究生和博士研究生。
主持在研和完成項目:
1. 主持國家自然科學基金《熒光信號釋放受分子邏輯門機制控制的新型靶向智能探針及熒光標記成像》21272172, 2013.1-2016.12
2. 主持國家自然科學基金《內部固有金屬催化位點的籠狀聚集體的構建及其對烷烴氧化反應的催化性能研究》20972111, 2010-2012.
3. 主持教育部新世紀優秀人才支持計劃《靶向紅外熒光探針及其在癌癥等重大疾病檢測中的應用》NCET-09-0894, 2009-2011.
4. 主持天津市自然科學基金重點項目《雙控制型智能熒光探針與腫瘤熒光標記成像》12JCZDJC21000, 2012.4-2015.3.
5. 主持完成天津市自然科學基金《基于新型杯[6]芳烴衍生物的全光子邏輯門器件》08JCYBJC26700, 2008-2010.
6. 主持完成教育部基金《基于新型杯[6]芳烴衍生物的全光子輸入/輸出分子邏輯門系統》(教外司留[2008]101號), 2008-2011.
7. 主持完成南開大學國家重點實驗室2008年-2012年連續5期開放基金《基于杯[6]芳烴的熒光受體分子器件的構建及性能研究》, 2008.1-2008。12.
8. 參與完成國家自然科學基金《具有金屬-金屬鍵雙金屬大環化合物合成及性能研究》20102003; 2002-2004.
9. 參與完成國家自然科學基金《生物調控活性鍺磷有機化合物的合成與性質研究》29572053, 1996-1998.
專利:
1. 一種具有核-殼結構的有機分子探針材料及其制備方法,發明專利公開號 CN101602942A
2. 一種含給電子基團半菁藍素溫敏分子光學探針的制備方法, 發明專利申請號 2013100220191
3. 一種含吸電子基團半菁藍素溫敏分子光學探針的制備方法,發明專利申請號 2013100218524
4. 一種半菁藍素硼酸分子熒光探針及其制備方法和應用,發明專利申請號2012105743088
5. 一種用于檢測次氯酸根的分子熒光探針及其制備和應用,發明專利申請號2012105741631
獲獎和榮譽稱號:
2009年,教育部新世紀優秀人才支持計劃人選,中華人民共和國教育部。NCET-09-0894
2006年,天津市自然科學獎二等獎,《超分子化學基礎研究—識別、組裝和化學傳感》2006ZR-2-002-R3,天津市人民政府。
2013年,天津市 “131”創新型人才培養工程第一層次人選。
發表論文:
1. Wang Q., Liu C., Lu Y., He S., Liu C., Zhao L., Zeng X., Novel Water Soluble Styrylquinolinium Boronic Acid as a Ratiometric Reagent for the Rapid Detection of Hypochlorite,Dyes and Pigments, 2013, 99, 733-739
2. Liu C., Lu Y., He S., Wang Q., Zhao L., Zeng X., The nature of the styrylindolium dye: transformations among monomer, aggregates and water adducts and its photophysical properties, J. Mater. Chem. C. 2013, 1, 4770-4778
3. Chang J., Lu Y., He S., Liu C., Zhao L., Zeng X., Efficient Fluorescent Chemosensor for HSO4- Based on a Strategy of Anion-Induced Rotation-Displaced H-Aggregate, Chem. Commun., 2013, 49, 6259-6261.
4. Cai S., Lu Y., He S., Wei F., Zhao L., Zeng X., A highly sensitive and selective turn-on fluorescent chemosensor for palladium based on a phosphine–rhodamine conjugate , Chem. Commun., 2013, 49, 822-824.
5. Li Y., He S., Lu Y., L. Zhao, Zeng X., Novel mercury sensor based on water soluble styrylindolium Dye, Dyes and Pigments, 2013, 96, 424-429.
6. Lu Y., Sun J., Wang L., Cheng D., Sun Y., Zeng X., Fluorescence turn-on detection of DNA based on the aggregation-induced emission of conjugated poly(pyridinium salt)s, Polym. Chem., 2013, 4, 4045-4051.
7. Han F., Lu Y., Zhang Q., Sun J., Zeng X., Li C., Homogeneous and sensitive DNA detection based on polyelectrolyte complexes of cationic conjugated poly(pyridinium salt)s and DNA, J. Mater. Chem., 2012, 22, 4106-4112.
8. Wei F., Lu Y., He S., Zhao L., Zeng X., Highly Sensitive Fluorescent Chemosensor for Hypochlorite Anion Based on a Novel Irreversible Ring-Opened Strategy, Anal. Methods, 2012, 4, 616-618
9. Wei F., Lu Y., He S., Zhao L., Zeng X., Selective and sensitive fluorescence chemosensor for the hypochlorite anion in water,J. Fluoresc.2012, 22, 1257–1262
10. 王煒何松陸燕曾憲順,基于杯[4]芳烴的銀離子熒光探針合成與性能,高等學校化學學報 ,2012,33,2470-2475
11. Lu Y., Huang S., Liu Y., He S., Zhao L. and Zeng X., Highly Selective and Sensitive Fluorescent Turn-on Chemosensor for Al3+ Based on a Novel Photoinduced Electron Transfer Approach, Org. Lett. 2011, 13, 5274-5277.
12. Zeng X., Bornholdt C., Over D., Reinaud O., Synthesis of “Two-Story” Calix[6]aza-Cryptands, Org. Lett. 2011, 13, 5660-5663
13. Li Y., He S., Lu Y., Zeng X., Novel Hemicyanine Dye as Colorimetric and Fluorometric Dual-modal Chemosensor for Mercury in Water, Org. Biomol. Chem. 2011, 9, 2606-2609
14. Huang S., He S., Lu Y., Wei F., Zeng X. and Zhao L., Highly sensitive and selective fluorescent chemosensor for Ag+ based on a coumarin-Se2N chelating conjugate, Chem. Commun. 2011, 47, 2408-2410.
15. 何松,陸陽,李園園,陸燕,曾憲順,基于C3v對稱性的杯[6]芳烴對Hg2+的熒光選擇性識別行為, 高等學校化學學報, 2011, 32: 2139-2144.
16. 李園園, 陸燕, 何松, 曾憲順,基于半青藍素修飾的汞離子探針比色傳感行為研究, 高等學校化學學報, 2011, 32: 2123-2127.
17. Ren Y., Li C., Lu Y., Wang X., Zeng X. Aggregates of cholic acid and benzylamine as templates for the formation of hollow silica spheres, J. Mater. Sci. 2010, 45, 6830–6833
18. Zeng X., Wang C., Batsanov A. S., Bryce M. R., Gigon J., Urasinska-Wojcik B., Ashwel G. J., Synthesis and Properties of Functionalized Oligo(arylene) Molecular Wires with Thiolated Termini: Competing Thiol-Au and Nitro-Au Assembly, J. Org. Chem. 2010, 75, 139-136.
20. Lu Y., Li Y., He S., Lu Y., Liu C., Zeng X., Chen L., Synthesis and properties of calix[4]arene telluropodant ethers as Ag+ selective sensors and Ag+, Hg2+ extractants, Beilstein J. Org. Chem. 2009, 5: 59
21. Lu Y., Xiao C., Yu Z., Zeng X., Ren Y., Li C., Poly(pyridinium) salts containing calix[4]arene segments in the main chain as potential biosensors, J. Mater. Chem. 2009, 19, 8796–8802
22. Liu L., Li X., Hou S., Xue Y., Yao Y., Ma Y., Feng X., He S., Lu Y., Wang Y., Zeng X. Nanoparticles from Block Copolymer Encapsulating Re(phen) complexes as Bifunctional Agents for Cell Imaging and Gene Transfection, Chem. Commun. 2009, 6759–6761.
23. Over O., Douziech B., de Lalande A., Zeng X., Parisel O., Le Mest Y., Reinaud O. Replacement of a nitrogen by a phosphorous donor in biomimetic copper complexes: a surprising but informative case study with calix[6]arene-based cryptands, Inorg. Chem. 2009, 48, 4317-4330,
24. Rothe C., Chiang C.-J., Jankus V., Abdullah K., Zeng X., Jitchati R., Batsanov A. S., Bryce M. R., Monkman A. P. Ionic Iridium(III) Complexes with Bulky Side Groups for Use in Light Emitting Cells (LECs) Reduction of Concentration Quenching, Adv. Funct. Mater. 2009, 19, 2038–2044.
25. Zeng X., Tavasli M., Perepichka I. F., Batsanov A. S., Bryce M. R., Chiang C.-J., Rothe C., Monkman A. P., Cationic Bis-cyclometalated Iridium(III) Phenanthroline Complexes with Pendant Fluorenyl Substituents: Synthesis, Redox, Photophysical Properties and Light-Emitting Cells, Chem. Eur. J. 2008, 14, 933-943.
26. 王吉有,曾憲順,袁芳,李南征, 3-倍半氧鍺基-N-(2-苯并噻唑基)丙酰胺和3-倍半氧鍺基-2-甲基-N-(2-苯并噻唑基)丙酰胺的拉曼光譜和紅外光譜研究, 光譜學與光譜分析, 2008, 28(10), 189-190.
27. 王吉有,曾憲順, 3-三苯基鍺基-1,1-二苯基-1-丙烯及其同系物的拉曼光譜和紅外光譜, 光散射學報, 2008, 20, 69-71.
28. Zeng X., Wang C., Bryce M. R., Batsanov A. S., Sirichantaropass S., Garcia-Suarez V. M., Lambert C. J., Sage I., Functionalized 8 nm Long Aryleneethynylene Molecular Wire with Alkyne Termini, Eur. J. Org. Chem. 2007, 5244–5249
29. Qin D., Zeng X., Li Q., Xu F., Song H., Zhang Z.-Z., Silver(I) N-Heterocyclic Carbene-Bridged Calix[4]arene Analogues as Efficient [60]Fullerene Receptor, Chem. Commun. 2007, 147-149.
30. Barker C. A., Zeng X., Bettington S., Batsanov A. S., Bryce M. R., Beeby A., Porphyrin, Phthalocyanine and Porphyrazine Derivatives with Multifluorenyl Substituents as Efficient Deep-Red Emitters, Chem. Eur. J. 2007, 13, 6710 – 6717.
31. Izzet G., Zeng X., Akdas H., Marrot J., Reinaud O., Drastic effects of the second coordination sphere on neutral vs. anionic guest binding to a biomimetic Cu(II) center embedded in a calix[6]aza-cryptand, Chem. Commun. 2007, 810-812.
32. Izzet G., Zeng X., Over D., Giorgi M., Jabin I., Le Mest Y., Reinaud O., First insights into the electronic properties of a Cu(II) center embedded in the PN3 cap of a calix[6]arene-based ligand. Inorg. Chem. 2007, 46, 375-377 (communication).
33. Zeng X., Batsanov S. A., Bryce M. R. Calix[6]arene Derivatives Selectively Functionalis-ed at Alternate Sites on the Smaller Rim with 2-Phenylpyridine and 2-Fluorenylpyridine Substituents to Provide Deep Cavities, J. Org. Chem. 2006, 71, 9589-9594.
34. Le Gac S., Zeng X., Girardot C., Jabin I., Efficient Syntheses and Host-guest Properties of Two New Calix[6]aza-cryptands, J. Org. Chem. 2006, 71, 9233-9236.
35. Zeng X., Coquiere, D., Alenda, A., Garrier, E., Prangé, T., Li, Y., Reinaud O., Jabin, I., Efficient Synthesis of Calix[6]tmpa: a New Calix[6]aza-cryptand with Original Conformational and Host-Guest Properties. Chem. Eur. J. 2006, 12, 6393-6402
36. Qin D., Zeng X.*, Liu C., Xu F., Li Q., Zhang Z., Mercury Selective Extraction by Novel Macrocyclic Calix[4](diseleno)crown-5 Ethers, Chin. J. Chem. 2006, 24, 674-680.
37. Darbost U., Zeng X., Giorgi M., Jabin I.: Optically Pure Calix[6]trisammoniums: Syntheses and Host-guest Properties toward Neutral Guests, J. Org. Chem. 2005, 70, 10552-10560
38. 盧春陽,王華芳,何錫文,陳朗星,李文友,曾憲順,張玉奎,杯芳烴衍生物和丙稀酰胺作為復合功能單體的分子印跡聚合物對海因類化合物的選擇性識別研究,高等學校化學學報,2005, 26, 1820-1824。
39. 呂鑒泉, 曾憲順, 艾娟, 龐代文, 鉗狀杯[4]芳烴為探針的固態PVC膜汞離子選擇性電極,高等學校化學學報, 2005, 26(2), 238-240.
40. Le Gac S., Zeng X., Reinaud O., Jabin I. Synthesis and Conformational Study of the First Triply Bridged Calix[6]azatubes, J. Org. Chem. 2005, 70, 1204-1210.
41. Darbost U., Zeng X., Rager M.-N., Giorgi M., Jabin I., Reinaud O., X-ray and Solution Structure of the First Zn Funnel Complex Based on a Calix[6]aza-cryptand. Eur. J. Inorg. Chem. 2004, 4371-4374.
42. Zeng X., Hucher, H., Reinaud O., Jabin, I.: A Novel Receptor Based on a C3v-Symmetrical PN3-calix[6]cryptand, J. Org. Chem. 2004, 69, 6886-6889
43. Liu C., Qing D., Leng X., Chen L., Zeng X., Xu F., Li Q., He X., Zhang, W., Zhang Z., Influences of Hard Donor on Cation Selectivities Closing to Soft Selenium Donor in Tweezer-like Calix[4]arene Receptors, Chin. J. Chem. 2004, 22, 804-810.
44. Lu J., Pang D., Zeng X., He X., A new solid-state silver ion-selective electrode based on a novel tweezer-type calixarene derivative. J. Electroanal. Chem. 2004, 568, 37-43.
45. Lu C., He H., He X., Zeng X., Molecularly Imprinted Polymer with Calix[4]arene Derivative for the Recognition of Acetanilide. Chin. J. Chem. 2004, 22, 275-278.
46. Xu F., Li Q., Zeng X., Leng X., Zhang Z., Bimetallocyclophanes Formed by the π- Stacking Interaction Approach and Fluorescent Chemosensing Behavior. Organometallics, 2004, 23; 632-634.
47. 荻曉威,何錫文,曾憲順,鄒本東,硒功能化杯芳烴載體銀離子選擇性膜電極的研究,分析化學,2004,32, 430-434.
48. Cui D., Zhao Y., Zeng X., Xu F., Leng X., Li Q., Zhang Z., Synthesis and crystal structure of Mo(CO)4(NNP) (NNP=2-(N-cyclohexyl-N- diphenylphosphinomethyl)aminopyridine). Jiegou Huaxue, 2003, 22, 297-300.
49. Li Q., Xu F., Cui D., Yu K., Zeng X., Leng X., Song H., Zhang Z., Heterobimetallic Pt(ii)-M(i) (M = Cu, Ag) eight-membered macrocyclic complexes with large-bite P,N-ligand bridges. Dalton Transactions, 2003, 1551-1557.
50. Zeng X., Sun H., Chen L., Leng X., Xu F., Li Q., He X., Zhang W., Zhang Z. -Z. Synthesis of a tweezer-like bis(arylthiaalkoxy)calix[4]arene as a cation sensor for ion-selective electrodes: an investigation of the influence of neighboring halogen atoms on cation selectivity. Org. Biomol. Chem. 2003, 1, 1073-1079.
51. 荻曉威,何錫文,曾憲順,硒功能化杯[4]芳烴對金屬離子的識別及在PVC基質支撐液膜的傳輸作用,化學學報,2003,61, 1854-1859.
53. Cui D. J., Zeng X., Leng X., Xu F., Zhang Z., trans-Tricarbonylbis[diphenyl(benzoylmethyl)- phos-phine]iron(0). Acta Crystal. E. 2003, E59, m546-m547.
54. Liu Q., Song H., Xu F., Li Q., Zeng X., Leng X., Zhang Z., Formation and crystal structures of 9-methylanthracene photodimer and iepidopterene. J. Chem. Res. (S), 2003, 445-447.
55. Cui D. J., Zeng X., Leng X., Xu F., Zhang Z., An unexpected product: di-η-iodo-bis{[2-(N-diphenyl-phosphinomethyl- N-cyclohexylamino)pyridine]iodomercury(II)}. Acta Crystal. E. 2003, E59, o868-o869.
56. Lu J., He X., Zeng X., Zhang H., Zhang Z., Anodic stripping voltammetric determination of lead(II) using glassy carbon electrode modified with novel calix[4]arene. Chin. J. Chem. 2003, 21, 687-692.
57. Liu Q., Song H., Xu F., Li Q., Zeng X., Leng X., Zhang Z., Synthesis, crystal structure and photophysical properties of N-heterocyclic carbene Pd(II), Pt(II) complexes and iodine adduct. Polyhedron , 2003, 22, 1515-1521.
58. Cui D., Zeng X., Leng X., Xu F., Zhang Z., {[N-Benzyl-N-(2-pyridyl)amino]methylene} diphenyl- phosphine oxide. Acta Crystal. E. 2003, E59, o679-o680.
60. Lu J., He X., Zeng X., Wan Q., Zhang Z., Voltammetric determination of mercury(II) in aqueous media using glassy carbon electrodes modified with novel calix[4]arene. Talanta, 2003, 59, 553-560.
61. Xu F., Li Q., Wu L., Leng X., Li Z., Zeng X., Chow Y., Zhang Z., Formation of Group 11 Metal(I)-Arene Complexes: Bonding Mode and Molecule-Responsive Spectral Variations. Organometallics, 2003, 22, 633-640.
62. 陳朗星,張佳,何錫文,曾憲順,張正之,杯芳烴衍生物液-液萃取和液膜傳輸銀的對比研究及機理探討,化學學報,2003,61, 104-109.
63. Liu Q., Xu F., Li Q., Zeng X., Leng X., Chou Y., Zhang Z., A Luminescent Silver(I) Carbene Stair Polymer. Organometallics, 2003, 22, 309-314.
64. Zeng X., Leng X., Chen L., Sun H., Xu F., Li Q., He X., Zhang Z., Novel bis(phenylseleno- alkoxy)calix[4]arene molecular tweezer receptors as sensors for ion-selective electrodes. J. Chem. Soc., Perkin Trans. 2, 2002, 796-801.
65. Xu F., Li Q., Zeng X., Leng X., Zhang Z., The Calix-Shaped Metallocyclophane [Rh{9,10-bis(2- (diphenylphosphino)ethyl) anthracene}(CO)Cl]3 and Its Solution Behavior. Organometallics, 2002, 21, 4894-4896.
66. Sun H., Zeng X. , Lu J., Leng X., Chen Q., Xu F., Li Q., He X., Zhang W., Zhang, Z., Synthesis of a tweezer-like bis(phenylthiapropoxy) calix[4]arene as a cation/π? enhanced sensor for ion-selective electrodes. Chin. J. Chem.,2002, 20, 1109-1114.
67. Liu Q., Xu F., Li Q., Zeng X., Leng X., Zhang Z., Preparation, structural characterization and luminescent property of binuclear silver(I) complex formed by benzotriazole and 1-hydroxymethylbenzotriazole. Chin. J. Chem.,2002, 20, 878-883.
68. Zeng X., Weng L., Chen L., Xu F., Li Q., Leng X., He X., Zhang Z. The syntheses and Ag+-selective electrode properties of benzothiazolylthiaalkoxy functionalized calix[4]arenes: an investigation of the structure-selectivity relationship in the ionophore-based ISEs. Tetrahedron, 2002, 58, 2647-2658.
69. Zeng X., Han X., Chen L., Li Q., Xu F., He X., Zhang Z. -Z. The first synthesis of a calix[4](diseleno)crown ether as a sensor for ion-selective electrodes. Tetrahedron Lett., 2002, 43, 131-134.
70. 柳清湘,徐鳳波,李慶山,曾憲順,張正之,硼酸極其衍生物在熒光分子開關中的應用,化學通報,2002, 65(10), 650-656.
71. Chen L., Ju H., Zeng X., He X., Zhang Z., Cesium selective electrodes based on novel double flexible spacers bridged biscalix[4]arenes. Anal. Chim. Acta, 2001, 447, 41-46.
72. Chen L., Ju H., Zeng X., He X., Zhang Z., Silver ion-selective electrodes based on novel containing benzothiazolyl calix[4]arene. Anal. Chim. Acta, 2001, 437, 191-197.
73. Zeng X., Weng L., Zhang Z., The first lower-rim O-arylation of calix[4]arenes. Chem. Lett., 2001, 550-551.
74. Zeng X., Weng L., Chen L., Ju H., Leng X., He X., Zhang Z., Synthesis and structure of novel double flexible spacer bridged biscalix[4]arenes. Chin. J. Chem.,2001, 19, 493-499.
75. Zeng X., Weng L., Chen L., Leng X., Ju H., He X., Zhang Z., The synthesis of some pyridyl functionalized calix[4]arenes as the sensor molecule for silver ion-selective electrodes. J. Chem. Soc., Perkin Trans. 2, 2001, 545-549.
76. 居紅芳, 陳朗星, 曾憲順, 何錫文, 張正之, 新型杯芳烴衍生物銀離子選擇電極的研究, 分析科學學報, 2001, 17, 446-450
77. Zeng X., Chen L., Weng L., Ju H., He X., Zhang Z., Syntheses and ion-selective properties of 25,27-bis(2-hydroxyethyl- thioalkoxyl)-26,28-dihydroxycalix[4]arenes. J. Chem. Res. (S), 2000,518-519.
78. 王吉有, 徐曉軒, 郭曙光, 金鵬, 張存洲, 曾憲順, 張正之, 3-三苯基鍺基-1,1-二苯基-1-丁醇類化合物的拉曼光譜和紅外光譜研究, 光譜與光譜分析, 2000, 20, 668-670.
79. Chen L., Zeng X., Ju H., He X., Zhang Z., Calixarene derivatives as the sensory molecules for silver ion-selective electrode. Microchem. J. 2000,65, 129-135.
80. Chen L., Zeng X., He X., Zhang Z., Selective electrodes for silver based on polymeric membranes containing calix[4]arene derivatives. Fresenius J. Anal. Chem., 2000,367, 535-538.
81. Zeng X., Weng L., Chen L., Leng X., Zhang Z., He X., Improved silver ion-selective electrodes using novel 1,3-bis(2-benzothiazolyl) thioalkoxy-p-tert-butylcalix[4]arenes. Tetrahedron Lett. 2000, 41, 4917-4921
82. 王吉有,曾憲順,孫麗娟,張正之,等 β-三氯鍺基丙酸類化合物的拉曼光譜和紅外光譜, 光散射學報,2000, 12(2), 90-93.
83. 王吉有,曾憲順,孫麗娟,張正之,等 2-三苯基鍺基乙基苯基酮、4-三氯鍺基-4-甲基-2-戊酮及其類似物Raman 及IR光譜, 光散射學報,2000,12(3),133-136。
84. 王吉有,曾憲順,孫麗娟,張正之,等 β-三苯鍺基丙酸及β-三苯鍺基丁酸的拉曼光譜和紅外光譜, 光散射學報,2000,12(3),137-141。
85. 汪清民, 曾憲順, 曾強, 黃潤秋. 四配位有機鍺化合物紅外光譜表征. 化學通報, 1999,13-19.
86. 曾憲順, 曾強, 崔濤, 汪清民, 多羥基有機鍺及有機鍺倍半氧化物的合成, 化學通報, 1999, 55-58.
87. 曾憲順, 曾強, 崔濤, 汪清民, 李東波, O-(3-三苯鍺基)正丙基硫代磷酸酯及類似物的合成, 化學學報, 1999, 57, 196-201.
88. Zeng Q., Zeng X., Wang Q., Cui T., Zhang Z., Synthesis and reactivity of 3-(trichlorogermyl)- propanoic acid and 3-(triphenylgermyl)propanoic acid. Chin. J. Chem. 1998, 16, 184-192.
89. 曾強; 曾憲順; 汪清民, 一種介嗎川的合成新方法, 合成化學, 1998, 6(1), 49-54.
90. Wang, Q.; Zeng, X; Cui, T.; Zeng, Q., Synthesis of novel organogermanium compounds containing phosphoryl groups and their bioactivities, Chem. J. Chin. Univ., 1998, 19, 358-359.
91. 曾強; 曾憲順; 崔濤; 汪清民. O-(3-三苯基鍺基)正丁基硫代磷酸酯類化合物的合成. 化學通報, 1998, 10, 46-47.
92. 曾強,汪清民,張中標,曾憲順,崔濤. 具有抗癌活性的含磷、鍺有機化合物的最新研究進展. 廣東微量元素科學, 1998, 5, 16-19.
93. 曾強;曾憲順; 汪清民;崔濤; 徐風波. 具有生物活性的有機鍺化合物的研究進展. 廣東微量元素科學, 1998, 5, 5-15.
94. 曾憲順, 汪清民, 崔濤, 曾強, β-(三氯鍺基)丙酸及β-三苯基丙酸與苯基溴化鎂的反應, 有機化學, 1998, 18, 538-541.
95. Wang, Q.; Zeng, X; Cui, T.; Zeng, Q., Synthesis of novel organogermanium sesquioxides and reactivities of 3-(trichlorogermyl)propanoic acid, Chem. J. Chin. Univ., 1998, 19, 356-357.
96. 范紀能; 曾憲順; 曾強β-(N-取代酰胺基)乙基倍半鍺氧化物的合成, 化學通報, 1997, 1, 33-36.
97. 曾強,汪清民,徐風波,曾憲順. 四配位有機鍺化合物的1H NMR表征. 波譜學雜志, 1997, 14, 267-274.
98. 曾強;曾憲順; 崔濤; 范紀能. 某些倍半鍺氧化物的合成及生物活性研究. 化學通報, 1996, 12, 30-34.
99. 范紀能,曾強,曾憲順 β-三氯鍺基丙酸及其衍生物的制備, 四川師范學院學報(自然科學版), 1996, 17, 46.
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