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Aqueous RAFT Polymerization of Imidazolium-Type Ionic Liquid Monomers: En Route to Poly(ionic liquid)-Based Nanoparticles through RAFT Polymerization-Induced Self-Assembly
作者:B. Zhang, X. Yan, P. Alcouffe, A. Charlot, E. Fleury, and J. Bernard.
關(guān)鍵字:Aqueous RAFT Polymerization,Imidazolium-Type Ionic Liquid,RAFT Polymerization-Induced Self-Assembly
論文來源:期刊
具體來源:ACS Macro Letters
發(fā)表時間:2015年

The synthesis by aqueous RAFT polymerization of hydrophilic narrowly dispersed imidazolium-based poly(ionic liquid)s (? typically below 1.20) is reported. Full monomer conversion is achieved within hours and high endgroup fidelity of the living end groups affords the preparation

of well-defined block copolymers. The resulting poly(ionic liquid) macroRAFT agents are finally exploited to polymerize 2-vinylpyridine in water and generate PIL-based nanoparticles of various morphologies (spheres, vesicles, or worms) in a onepot surfactant-free process.


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