[Polym. Chem.] Polymer Brushes on Metal–Organic Frameworks by UV-Induced Photopolymerization
作者：Liman Hou, Lei Wang, Ning Zhang,* Zhigang Xie and Dewen Dong
關鍵字：MOF, polymer brushes, UV-induced photopolymerization
論文來源：期刊
具體來源：Polymer Chemistry
發(fā)表時間：2016年
Metal–organic frameworks (MOFs) are extremely promising candidates for application in diverse fields. However, a limitation to the widespread use of MOFs is the absence of a facile and efficient chemical modification method which can greatly improve their poor processability and stability without altering the inherent outstanding chemical and physical properties. Herein, we report a universal post-synthetic modification strategy by directly forming polymer brushes on MOF surface without any premodification or immobilization of initiators via UV-induced photopolymerization. The method is applicable to a series of representative MOFs, allowing the creation of polymer brushes on the exterior surface of nanoMOFs and MOF membranes. Characterization of the polymer brushes indicates a high grafting density of grafted polymer chains, thus endowing MOFs with improved thermal/chemical stabilities with the inner chemical structure and porosity intact. Moreover, the polymer modification facilitates an efficient removal of organic dyes from water solutions.