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Construction of a ratiometric electrochemical sensor for Bisphenol A detection by coupling nonionic surfactant-decorated conductive carbon black with ferricyanide probe
作者:Zong-Xian Zhu , Xuan Zhang
關鍵字:Ratiometric electrochemical sensorConductive carbon blackNonionic surfactantBisphenol A
論文來源:期刊
具體來源:Talanta 2025, 283, 127084.
發(fā)表時間:2025年

In this work, a novel ratiometric electrochemical sensor for bisphenol A (BPA) detection was facilely constructed by coupling conductive carbon black (VXC-72R) with ferricyanide probe. The VXC-72R was decorated with nonionic surfactant Tween to enhance the sensitivity and coated on glassy carbon electrode (GCE), whereas K3[Fe(CN)6] was introduced into electrolyte solution as an internal reference probe to realize dual-signal outputs. The present ratiometric electrochemical sensor achieved a highly sensitive and selective detection of BPA in PBS solution (pH = 7.0), with a linear range of 0.08–40.0 μM and detection limit of 0.05 μM. Moreover, it has been successfully applied to the determination of BPA in real lake water and milk samples with the satisfactory recoveries rates of 94.8–102.3 %.



https://doi.org/10.1016/j.talanta.2024.127084



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