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Study on Structure and Properties of PLA/PBS in-situ Reinforced Blends Prepared by Vane Extruder  
Study on Structure and Properties of PLA/PBS in-situ Reinforced Blends Prepared by Vane Extruder
資料類型: PDF文件
關鍵詞: pla  pbs  in-situ  reinforced  blends  vane  extruder  
資料大小: 109K
所屬學科: 分子表征
來源: 第六屆亞歐研討會上處理和性能增強聚合物會議文集(2013.6.2-6 武漢)
簡介:
Withtheresearchanddevelopmentofhighperformancepolymermaterials,theproblemsofresources9environmentandenergymustbeconsideredinordertorealizesustainabledevelopmentofpolymerindustry.Therefore,itisadevelopmenttrendtoexploitanovelhighperformancebiodegradablepolymerfromrenewableresources.Anewblendingmethodhasbeenconcernedinrecentresearchanddevelopmentefforts,whichisemployedtogeneratesomedeformeddispersedphaseinsituduringbiodegradablepolymerblendingprocessingwithphysicalandchemicalmeansorexternalfieldchange.Itiswellprovedthatthedeformedmorphologyismoreeasilyrealizedinelongationalforcefieldinwhichthevelocitygradientisparallelwiththeconveyingdirection.Inordertoachievetheprocessbasedontheelongationalforcefield,QU[l‘2]designedapolymerprocessingequipmentdesignatedasvaneextruderinwhichthepolymerparticulatesareplasticizedandconveyedbynormalstress.Thevolumeelongationalforcefieldcanbegeneratedbyperiodicallychangingofthecavityvolumeinthevaneplasticatingandconveyingunits(VPCUs).ThroughthecontinuousmotionofthepolymermaterialsintheadjacentVPCUs,itcangenerateacontinuousvolumeelongationalforcefieldinthepolymerplasticatingandconveyingprocess.Inthisstudy,avaneextruderisemployedtopreparePoly(lacticacid)/Poly(butylenesuccinate)trulybiodegradablein-situreinforcedblendsunderdifferentprocessingparameters(temperatureandtimes)andthemorphologies,thermalpropertiesandmechanicalpropertiesofblendspreparedareanalyzed.MorphologicalobservationindicatedthatwithincreasingtheprocessingtimesthePLAparticlesizeofblendsbecamesmallerandtheshapeofthefracturesurfaceofPLAshowedovalshapeandlongstripundergoinglowtemperatureprocessing.TGAthermogramsshowedthattheorientedPLAdispersedwellinthematrixofPBSretardedtheflame.MechanicalstudiesrevealedthePLA/PBSblendsoflowtemperatureprocessingexhibitedoptimumelongationatbreakaswellastensilemodulus,tensilestrengthandimpactstrength,whichimpliesthatthein-situreinforcementofblendsisrealizedduringprocess.
作者: J. P. Qu, H. Z. Chen, G. Z. Zhang
上傳時間: 2013-06-21 14:57:38
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