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Preparation,Characterization and Properries of in-situ formed Graphene Oxide/Phenol Formaldehyde Nanocomposites  
Preparation,Characterization and Properries of in-situ formed Graphene Oxide/Phenol Formaldehyde Nanocomposites
資料類型: PDF文件
關鍵詞: graphene  oxide  phenol  formaldehyde  nanocomposites  in-situ  polymerization  
資料大小: 107K
所屬學科: 分子表征
來源: 第六屆亞歐研討會上處理和性能增強聚合物會議文集(2013.6.2-6 武漢)
簡介:
Phenolformaldehyde(PF)resinhasbeenwidelyusedinbuildingvariousfunctionalstructurematerialsandcoatingsduetotheirhighmechanicalstrength,electricalinsulating,flameretardantresistance,fumingrateaswellastheirdimensionstability.However,itstillsuffersfromthebrittlenessandoxidationrisksbecauseoftheirspecialmethylene-phenolicstructure.ThusmanyresearchersarenowtryingtofindgoodsolutionstoenhancethemechanicalandthethermalpropertiesofPFresin.GrapheneOxide(GO),oneofthemostimportantderivativesofgraphene,isstructurallysimilartographene.However,thesurfaceofGOcontainslargenumbersofhydrophilicfunctionalgroups,suchascarbonyl,carboxyl,epoxyandhydroxyl,whichaffordedGOwithexcellentprocessability,dispersibilityandthecompatibilitywiththepolymer,thusGObecomesapromisingfunctionalnano-reinforcingmaterialforvariouspolymerandorganicmoleculestoapproachdifferentadvancedapplications.Inthiswork,grapheneoxide(GO)wasincorporatedintophenolformaldehyde(PF)resinbyin-situpolymerization.ThemorphologiesandpropertiesofGOsheetswerecharacterizedbyFTIR,XRD,andAFMmethods.ThestructureandpropertiesoftheGO/PFnanocompositeswerecharacterizedusingFTIR,XRD,DSCandTGAmethods.EffectsofGOcontent,reactiveconditions,andblendingmethodsonthestructureandpropertiesofGO/PFnanocompositeshavebeenstudied.ItwasfoundthatduetothewelldispersionofGOsheetsinpolymermatrixandthestronginterfacialinteractionbetweentheGOsheetsandPFmatrix,thethermalstabilityandthermalmechanicalpropertiesoftheGO/PFnanocompositesweregreatlyenhanced.
作者: W. H. Xu, C. Wei , J. Lv , H. X. Liu
上傳時間: 2013-07-01 14:46:15
下載次數: 1
消耗積分: 2  
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