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Vacuum Infusion Thermoplastic Composites for Natural Fiber Fabric Reinforced Anionic Polyamide-6  
Vacuum Infusion Thermoplastic Composites for Natural Fiber Fabric Reinforced Anionic Polyamide-6
資料類型: PDF文件
關鍵詞: vacuum  infusion  process  anionic  polyae-6  natural  fiber  
fabric  performance  
資料大小: 108K
所屬學科: 分子表征
來源: 第六屆亞歐研討會上處理和性能增強聚合物會議文集(2013.6.2-6 武漢)
簡介:
Inordertomanufacturelarger,thicker,morehomogeneousandcomplicatedthermoplasticcompositesthancurrentlycanbeachievedbymeltprocessing,avacuuminfusionprocessiscurrentlybeingdevelopedusingareactivethermoplasticpolymercalledanionicpolyamide-6(APA-6).Inpreviousstudiesitwasprovedthattheanionicpolyamide-6(APA-6)resinthatisusedhasexcellentmechanicalproperties.Naturalfiber,asakindoflowcost,lightweight,highspecificstrengthandstiffness,andnaturaldegradationofenvironment-friendlymaterial,usedinreinforcedcompositesiswidelyconcerned.However,nonaturalfiberreinforcedreactivethermoplasticpolymergradeshavebeenpreparedsofar.ThemainreasonistheapparentlypolymerizedbarrierbetweennaturalfiberandtheAPA-6,whichresultsinincompletepolymerizationwhenputtogether.Firstly,thereactionmechanisminthein-situpolymerizationprocessofnaturalfiber-reinforcedAPA-6wasdiscussedbycastingprocess.ItwasshownthatthelargenumberofhighlyreactivehydroxylonthesurfaceofnaturalfiberproducedaseriousbarriertoAPA-6,andthefiberbecamedarkbrown.Inordertosolvetheproblem,amethodwasadoptedbyusingalow-activityinitiatorcalledcaprolactammagnesiumbromide,whichhadinertreactivityandweaklyalkaline,limitedthereactionwiththehydroxylgroupsonthecellulose.Itwouldreducetheconsumptionoftheinitiator.Thustheinhibitorrolehasbeensignificantlyimproved.Thenasuitablemorphologicalstructureoffiberfabricwasselectedtoyieldintegratedcompositeswithanaveragethicknessof2.5mmandafiberweightcontentof40%byvacuuminfusionprocess.Thesoxhletextractionanddifferentialscanningcalorimeter(DSC)measurementsrespectivelysuggestedthedegreeofconversionandcrystallizationofcompositeswashigher.RemarkableimprovementofmechanicalpropertieswasachievedforAPA-6/naturalfibercompositesthroughdynamicmechanicalanalysis(DMA)andthree-pointbendingtest.Favorableinterfacialadhesionandwettabilitywererevealedbyscanningelectronmicroscopy(SEM)observation.
作者: Z. Kan,P. Chen, M. B. Yang
上傳時間: 2013-07-02 15:46:22
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